! ! Please cite as: ! T. Zirwes, T. Häber, F. Zhang, H. Kosaka, A. Dreizler, M. Steinhausen, ! C. Hasse, A. Stagni, D. Trimis, R. Suntz, H. Bockhorn ! "Numerical study of quenching distances using detailed diffusion and chemistry" ! Flow, Turbulence and Combustion, 2020. doi: https://doi.org/10.1007/s10494-020-00215-0 ! ! Reduced kinetic mechanism of CH4 combustion ! Operating conditions: ! -> Equivalence ratio: 0.75 - 1 ! -> P = 1 atm ! ! Obtained via DoctorSMOKE++ software: ! A. Stagni, A. Frassoldati, A. Cuoci, T. Faravelli, E. Ranzi ! "Skeletal mechanism reduction through species-targeted sensitivity analysis" ! Combustion and Flame, 163, 382-393 (2016). ! ! CHEMKIN format ! ELEMENTS C H O N END SPECIES N2 H2 H O2 O H2O OH H2O2 HO2 CO CO2 CH4 CH3 CH2 CH2(S) CH CH3O2H CH3O2 CH3OH CH3O CH2O HCO C2H6 C2H5 C2H4 C2H3 END REACTIONS H2+M=2H+M 4.5770e+19 -1.400 104400.00 H2/ 2.50/ H2O/ 12.00/ CO/ 1.90/ CO2/ 3.80/ CH4/ 2.00/ C2H6/ 3.00/ H2+O=H+OH 5.0800e+04 2.670 6292.00 H2+OH=H+H2O 4.3800e+13 0.000 6990.00 2O+M=O2+M 6.1650e+15 -0.500 0.00 H2/ 2.50/ H2O/ 12.00/ CO/ 1.90/ CO2/ 3.80/ CH4/ 2.00/ C2H6/ 3.00/ H+O2=O+OH 1.1400e+14 0.000 15286.00 H+OH+M=H2O+M 3.5000e+22 -2.000 0.00 H2/ 0.73/ H2O/ 3.65/ CH4/ 2.00/ C2H6/ 3.00/ O+H2O=2OH 6.7000e+07 1.704 14986.80 H+O+M=OH+M 4.7140e+18 -1.000 0.00 H2/ 2.50/ H2O/ 12.00/ CO/ 1.50/ CO2/ 2.00/ CH4/ 2.00/ C2H6/ 3.00/ H2O2(+M)=2OH(+M) 2.0000e+12 0.900 48749.00 LOW/ 2.49e+24 -2.300 48749.0/ TROE/ 0.4300 1.000e-30 1.000e+30/ H2O/ 7.65/ CO2/ 1.60/ N2/ 1.50/ O2/ 1.20/ H2O2/ 7.70/ H2/ 3.70/ CO/ 2.80/ H+H2O2=H2O+OH 2.4100e+13 0.000 3970.00 H+H2O2=H2+HO2 2.1500e+10 1.000 6000.00 O+H2O2=OH+HO2 9.5500e+06 2.000 3970.00 OH+H2O2=H2O+HO2 1.7400e+12 0.000 318.00 DUPLICATE OH+H2O2=H2O+HO2 7.5900e+13 0.000 7269.00 DUPLICATE H+HO2=2OH 7.0790e+13 0.000 295.00 H+HO2=H2+O2 1.1402e+10 1.083 553.78 O+HO2=O2+OH 3.2500e+13 0.000 0.00 OH+HO2=O2+H2O 7.0000e+12 0.000 -1092.96 DUPLICATE OH+HO2=O2+H2O 4.5000e+14 0.000 10929.60 DUPLICATE 2HO2=O2+H2O2 1.0000e+14 0.000 11040.88 DUPLICATE 2HO2=O2+H2O2 1.9000e+11 0.000 -1408.92 DUPLICATE H+O2(+M)=HO2(+M) 4.6500e+12 0.440 0.00 LOW/ 1.74e+19 -1.230 0.0/ TROE/ 0.6700 1.000e-30 1.000e+30 1.000e+30/ H2/ 1.30/ CO/ 1.90/ CO2/ 3.80/ H2O/ 10.00/ CH4/ 2.00/ C2H6/ 3.00/ O+CO(+M)=CO2(+M) 1.3620e+10 0.000 2384.00 LOW/ 1.17e+24 -2.790 4191.0/ H2/ 2.00/ H2O/ 12.00/ CO/ 1.75/ CO2/ 3.60/ OH+CO=H+CO2 7.0150e+04 2.053 -355.70 DUPLICATE OH+CO=H+CO2 5.7570e+12 -0.664 331.80 DUPLICATE HO2+CO=OH+CO2 1.5700e+05 2.180 17940.00 O2+CO=O+CO2 1.1190e+12 0.000 47700.00 H+CH3(+M)=CH4(+M) 1.2700e+16 -0.630 383.00 LOW/ 2.48e+33 -4.760 2440.0/ TROE/ 0.7830 74.00 2941. 6964./ H2/ 2.00/ H2O/ 6.00/ CO/ 1.50/ CO2/ 2.00/ CH4/ 2.00/ C2H6/ 3.00/ H+CH4=H2+CH3 6.1400e+05 2.500 9587.00 O+CH4=OH+CH3 1.0200e+09 1.500 8600.00 OH+CH4=H2O+CH3 5.8300e+04 2.600 2190.00 HO2+CH4=H2O2+CH3 1.1300e+01 3.740 21010.00 CH4+CH3O2=CH3+CH3O2H 9.6000e-01 3.770 17810.00 HO2+CH3=O2+CH4 1.1600e+05 2.230 -3022.00 CH4+CH2=2CH3 2.4600e+06 2.000 8270.00 N2+CH2(S)=N2+CH2 1.5000e+13 0.000 600.00 H2O+CH2(S)=H2O+CH2 3.0000e+13 0.000 0.00 CO+CH2(S)=CO+CH2 9.0000e+12 0.000 0.00 CO2+CH2(S)=CO2+CH2 7.0000e+12 0.000 0.00 O2+CH2(S)=>H+OH+CO 2.8000e+13 0.000 0.00 O2+CH2(S)=H2O+CO 1.2000e+13 0.000 0.00 O+CH2(S)=H2+CO 1.5000e+13 0.000 0.00 O+CH2(S)=H+HCO 1.5000e+13 0.000 0.00 H2+CH2(S)=H+CH3 7.0000e+13 0.000 0.00 H+CH2(S)=H2+CH 3.0000e+13 0.000 0.00 OH+CH2(S)=H+CH2O 3.0000e+13 0.000 0.00 CO2+CH2(S)=CO+CH2O 1.4000e+13 0.000 0.00 H+CH2(+M)=CH3(+M) 2.5000e+16 -0.800 0.00 LOW/ 3.20e+27 -3.140 1230.0/ TROE/ 0.6800 78.00 1995. 5590./ H2/ 2.00/ H2O/ 6.00/ CO/ 1.50/ CO2/ 2.00/ CH4/ 2.00/ C2H6/ 3.00/ O2+CH2=OH+HCO 1.0600e+13 0.000 1500.00 O2+CH2=>2H+CO2 2.6400e+12 0.000 1500.00 O+CH2=>2H+CO 5.0000e+13 0.000 0.00 H+CH2=H2+CH 3.0000e+13 0.000 0.00 OH+CH2=H2O+CH 1.1300e+07 2.000 3000.00 O2+CH=O+HCO 3.3000e+13 0.000 0.00 O+CH=H+CO 5.7000e+13 0.000 0.00 OH+CH=H+HCO 3.0000e+13 0.000 0.00 H2O+CH=H+CH2O 1.7740e+16 -1.220 23.80 CO2+CH=CO+HCO 1.7000e+12 0.000 685.00 O2+CH3(+M)=CH3O2(+M) 7.8120e+09 0.900 0.00 LOW/ 6.85e+24 -3.000 0.0/ TROE/ 0.6000 1000. 70.00 1700./ O2+CH3=O+CH3O 7.5460e+12 0.000 28320.00 O2+CH3=OH+CH2O 2.6410e+00 3.283 8105.00 O+CH3=H+CH2O 5.5400e+13 0.050 -136.00 OH+CH3=H2O+CH2(S) 4.9360e+14 -0.669 -445.80 PLOG / 1.000000e-02 4.936000e+14 -6.690000e-01 -4.458000e+02 / PLOG / 1.000000e-01 1.207000e+15 -7.780000e-01 -1.756000e+02 / PLOG / 1.000000e+00 5.282000e+17 -1.518000e+00 1.772000e+03 / PLOG / 1.000000e+01 4.788000e+23 -3.155000e+00 7.003000e+03 / PLOG / 1.000000e+02 8.433000e+19 -1.962000e+00 8.244000e+03 / OH+CH3=H2+CH2O 3.5020e+05 1.441 -3244.00 PLOG / 1.000000e-02 3.502000e+05 1.441000e+00 -3.244000e+03 / PLOG / 1.000000e-01 8.854000e+05 1.327000e+00 -2.975000e+03 / PLOG / 1.000000e+00 1.650000e+07 9.730000e-01 -2.010000e+03 / PLOG / 1.000000e+01 5.374000e+09 2.870000e-01 2.800000e+02 / PLOG / 1.000000e+02 9.494000e+18 -2.199000e+00 9.769000e+03 / OH+CH3=H+CH3O 1.1860e+09 1.016 11940.00 PLOG / 1.000000e-02 1.186000e+09 1.016000e+00 1.194000e+04 / PLOG / 1.000000e-01 1.188000e+09 1.016000e+00 1.194000e+04 / PLOG / 1.000000e+00 1.230000e+09 1.011000e+00 1.195000e+04 / PLOG / 1.000000e+01 1.798000e+09 9.650000e-01 1.206000e+04 / PLOG / 1.000000e+02 5.242000e+10 5.510000e-01 1.307000e+04 / OH+CH3=H2O+CH2 4.2930e+04 2.568 3997.80 HO2+CH3=OH+CH3O 1.0000e+12 0.269 -687.50 O+CH3O2=O2+CH3O 3.6000e+13 0.000 0.00 H+CH3O2=OH+CH3O 9.6000e+13 0.000 0.00 OH+CH3O2=O2+CH3OH 6.0000e+13 0.000 0.00 HO2+CH3O2=O2+CH3O2H 2.4700e+11 0.000 -1570.00 H2O2+CH3O2=HO2+CH3O2H 2.4100e+12 0.000 9936.00 CH3+CH3O2=2CH3O 5.0800e+12 0.000 -1411.00 2CH3O2=>O2+CH3OH+CH2O 3.1100e+14 -1.610 -1051.00 2CH3O2=>O2+2CH3O 1.4000e+16 -1.610 1860.00 H2+CH3O2=H+CH3O2H 1.5000e+14 0.000 26030.00 CH3O2H=OH+CH3O 6.3100e+14 0.000 42300.00 CH3OH(+M)=OH+CH3(+M) 2.0840e+18 -0.615 92540.60 LOW/ 1.50e+43 -6.995 97992.2/ TROE/ -0.4748 3.558e+04 1116. 9023./ CH3OH(+M)=H2O+CH2(S)(+M) 3.1210e+18 -1.017 91712.00 LOW/ 1.43e+47 -8.227 99417.1/ TROE/ 2.545 3290. 4.732e+04 4.711e+04/ H+CH3OH=H2+CH3O 1.9900e+05 2.560 10300.00 O+CH3OH=OH+CH3O 3.8800e+04 2.500 3080.00 OH+CH3OH=H2O+CH3O 1.5000e+02 3.030 -763.00 O2+CH3OH=HO2+CH3O 3.5800e+04 2.270 42764.50 HO2+CH3OH=H2O2+CH3O 1.2200e+12 0.000 20070.70 CH3+CH3OH=CH4+CH3O 3.2200e+03 2.425 8579.50 O2+CH3O=HO2+CH2O 4.3800e-19 9.500 -5501.00 H+CH3O=H2+CH2O 2.0000e+13 0.000 0.00 HO2+CH3O=H2O2+CH2O 3.0100e+11 0.000 0.00 CH3+CH3O=CH4+CH2O 1.2000e+13 0.000 0.00 2CH3O=CH3OH+CH2O 6.0300e+13 0.000 0.00 H+HCO(+M)=CH2O(+M) 1.0900e+12 0.480 -260.00 LOW/ 1.35e+24 -2.570 1425.0/ TROE/ 0.7824 271.0 2755. 6570./ H2/ 2.00/ H2O/ 6.00/ CO/ 1.50/ CO2/ 2.00/ CH4/ 2.00/ C2H6/ 3.00/ H2+CO(+M)=CH2O(+M) 4.3000e+07 1.500 79600.00 LOW/ 5.07e+27 -3.420 84348.0/ TROE/ 0.9320 197.0 1540. 1.030e+04/ H2/ 2.00/ H2O/ 6.00/ CO/ 1.50/ CO2/ 2.00/ CH4/ 2.00/ C2H6/ 3.00/ O2+CH2O=HO2+HCO 8.0700e+15 0.000 53420.00 O+CH2O=OH+HCO 6.2600e+09 1.150 2260.00 H+CH2O=H2+HCO 5.7400e+07 1.900 2740.00 OH+CH2O=H2O+HCO 7.8200e+07 1.630 -1055.00 HO2+CH2O=H2O2+HCO 1.8800e+04 2.700 11520.00 CH3+CH2O=CH4+HCO 3.8300e+01 3.360 4312.00 CH3O+CH2O=CH3OH+HCO 6.6200e+11 0.000 2294.00 CH3O2+CH2O=CH3O2H+HCO 1.9900e+12 0.000 11660.00 HCO+M=H+CO+M 5.7000e+11 0.660 14870.00 H2/ 2.00/ H2O/ 6.00/ CO/ 1.50/ CO2/ 2.00/ CH4/ 2.00/ C2H6/ 3.00/ O2+HCO=HO2+CO 7.5800e+12 0.000 410.00 O+HCO=OH+CO 3.0200e+13 0.000 0.00 H+HCO=H2+CO 7.3400e+13 0.000 0.00 OH+HCO=H2O+CO 3.0110e+13 0.000 0.00 CH3+HCO=CO+CH4 2.6500e+13 0.000 0.00 2HCO=CO+CH2O 1.8000e+13 0.000 0.00 O+HCO=H+CO2 3.0000e+13 0.000 0.00 HO2+HCO=>H+OH+CO2 3.0000e+13 0.000 0.00 2HCO=>H2+2CO 3.0000e+12 0.000 0.00 CH3O(+M)=H+CH2O(+M) 6.8000e+13 0.000 26170.00 LOW/ 1.87e+25 -3.000 24307.0/ TROE/ 0.9000 2500. 1300. 1.000e+99/ H2/ 2.00/ H2O/ 6.00/ CO/ 1.50/ CO2/ 2.00/ CH4/ 2.00/ C2H6/ 3.00/ 2CH3(+M)=C2H6(+M) 2.2770e+15 -0.690 174.90 LOW/ 8.05e+31 -3.750 981.6/ TROE/ 0.000 570.0 1.000e+30 1.000e+30/ H2O/ 5.00/ CO/ 2.00/ CO2/ 3.00/ H+C2H5(+M)=C2H6(+M) 5.2100e+17 -0.990 1580.00 LOW/ 1.99e+41 -7.080 6685.0/ TROE/ 0.8420 125.0 2219. 6882./ H2/ 2.00/ H2O/ 6.00/ CO/ 1.50/ CO2/ 2.00/ CH4/ 2.00/ C2H6/ 3.00/ O2+C2H6=HO2+C2H5 6.0300e+13 0.000 51870.00 O+C2H6=OH+C2H5 3.5500e+06 2.400 5830.00 H+C2H6=H2+C2H5 1.1500e+08 1.900 7530.00 OH+C2H6=H2O+C2H5 1.4800e+07 1.900 950.00 HO2+C2H6=H2O2+C2H5 3.4600e+01 3.610 16920.00 CH+C2H6=CH2+C2H5 1.1000e+14 0.000 -260.00 CH2(S)+C2H6=CH3+C2H5 1.2000e+14 0.000 0.00 CH3+C2H6=CH4+C2H5 5.5500e-04 4.720 3231.00 CH3O+C2H6=CH3OH+C2H5 2.4100e+11 0.000 7090.00 CH3O2+C2H6=CH3O2H+C2H5 1.9400e+01 3.640 17100.00 H+C2H4(+M)=C2H5(+M) 9.5690e+08 1.463 1355.00 LOW/ 1.42e+39 -6.642 5769.0/ TROE/ -0.5690 299.0 -9147. 152.4/ H2/ 2.00/ H2O/ 6.00/ CH4/ 2.00/ CO/ 1.50/ CO2/ 2.00/ C2H6/ 3.00/ H+C2H5=H2+C2H4 2.0000e+12 0.000 0.00 2C2H4=C2H5+C2H3 4.8200e+14 0.000 71530.00 CH3+C2H5=CH4+C2H4 1.1800e+04 2.450 -2921.00 2CH3=H+C2H5 4.7400e+12 0.105 10664.30 PLOG / 1.000000e-02 4.740000e+12 1.050000e-01 1.066430e+04 / PLOG / 1.000000e-01 2.570000e+13 -9.600000e-02 1.140610e+04 / PLOG / 1.000000e+00 3.100000e+14 -3.620000e-01 1.337250e+04 / PLOG / 1.000000e+01 2.150000e+10 8.850000e-01 1.353250e+04 / PLOG / 1.000000e+02 1.032000e+02 3.230000e+00 1.123610e+04 / O2+C2H5=HO2+C2H4 2.0940e+09 0.490 -391.40 PLOG / 4.000000e-02 2.094000e+09 4.900000e-01 -3.914000e+02 / PLOG / 1.000000e+00 1.843000e+07 1.130000e+00 -7.206000e+02 / PLOG / 1.000000e+01 7.561000e+14 -1.010000e+00 4.749000e+03 / H+C2H3(+M)=C2H4(+M) 6.0800e+12 0.270 280.00 LOW/ 1.40e+30 -3.860 3320.0/ TROE/ 0.7820 207.5 2663. 6095./ H2/ 2.00/ H2O/ 6.00/ CO/ 1.50/ CO2/ 2.00/ CH4/ 2.00/ C2H6/ 3.00/ O2+C2H4=HO2+C2H3 4.2200e+13 0.000 57623.10 H+C2H4=H2+C2H3 5.0700e+07 1.930 12950.00 OH+C2H4=H2O+C2H3 2.2300e+04 2.745 2215.50 CH3O+C2H4=CH3OH+C2H3 1.2000e+11 0.000 6750.00 CH3O2+C2H4=CH3O2H+C2H3 8.5900e+00 3.754 27132.00 CH3+C2H4=CH4+C2H3 9.7600e+02 2.947 15148.00 DUPLICATE CH3+C2H4=CH4+C2H3 8.1300e-05 4.417 8835.80 DUPLICATE O+C2H4=CH3+HCO 7.4530e+06 1.880 183.00 CH4+CH=H+C2H4 6.0000e+13 0.000 0.00 CH3+CH2(S)=H+C2H4 2.0000e+13 0.000 0.00 OH+C2H4=CH3+CH2O 5.3500e+00 2.920 -1732.70 PLOG / 1.000000e-02 5.350000e+00 2.920000e+00 -1.732700e+03 / PLOG / 2.500000e-02 3.190000e+01 2.710000e+00 -1.172300e+03 / PLOG / 1.000000e-01 5.550000e+02 2.360000e+00 -1.808000e+02 / PLOG / 1.000000e+00 1.780000e+05 1.680000e+00 2.060500e+03 / PLOG / 1.000000e+01 2.370000e+09 5.600000e-01 6.006700e+03 / PLOG / 1.000000e+02 2.760000e+13 -5.000000e-01 1.145510e+04 / O2+C2H3=CH2O+HCO 1.1600e+16 -1.130 3791.00 DUPLICATE PLOG / 1.000000e-02 2.490000e+36 -7.600000e+00 1.264000e+04 / PLOG / 1.000000e-01 2.430000e+36 -7.600000e+00 1.261000e+04 / PLOG / 3.160000e-01 1.950000e+36 -7.570000e+00 1.249000e+04 / PLOG / 1.000000e+00 2.730000e+35 -7.320000e+00 1.182000e+04 / PLOG / 3.160000e+00 1.430000e+36 -7.470000e+00 1.246000e+04 / PLOG / 1.000000e+01 5.180000e+35 -7.200000e+00 1.343000e+04 / PLOG / 3.160000e+01 3.190000e+20 -2.570000e+00 5.578000e+03 / PLOG / 1.000000e+02 2.730000e+33 -6.280000e+00 1.600000e+04 / O2+C2H3=CH2O+HCO 1.1600e+16 -1.130 3791.00 DUPLICATE PLOG / 1.000000e-02 4.540000e+15 -1.280000e+00 5.153000e+02 / PLOG / 1.000000e-01 4.590000e+15 -1.280000e+00 5.130000e+02 / PLOG / 3.160000e-01 4.810000e+15 -1.290000e+00 5.206000e+02 / PLOG / 1.000000e+00 6.080000e+15 -1.310000e+00 6.457000e+02 / PLOG / 3.160000e+00 9.450000e+15 -1.360000e+00 1.066000e+03 / PLOG / 1.000000e+01 2.560000e+15 -1.180000e+00 1.429000e+03 / PLOG / 3.160000e+01 1.030000e+69 -1.923000e+01 1.476000e+04 / PLOG / 1.000000e+02 4.210000e+10 1.900000e-01 8.306000e+02 / O2+C2H3=>H+CO+CH2O 1.1600e+16 -1.130 3791.00 DUPLICATE PLOG / 1.000000e-02 5.820000e+36 -7.600000e+00 1.264000e+04 / PLOG / 1.000000e-01 5.660000e+36 -7.600000e+00 1.261000e+04 / PLOG / 3.160000e-01 4.550000e+36 -7.570000e+00 1.249000e+04 / PLOG / 1.000000e+00 6.360000e+35 -7.320000e+00 1.182000e+04 / PLOG / 3.160000e+00 3.350000e+36 -7.470000e+00 1.246000e+04 / PLOG / 1.000000e+01 1.210000e+36 -7.200000e+00 1.343000e+04 / PLOG / 3.160000e+01 7.430000e+20 -2.570000e+00 5.578000e+03 / PLOG / 1.000000e+02 6.360000e+33 -6.280000e+00 1.600000e+04 / O2+C2H3=>H+CO+CH2O 1.1600e+16 -1.130 3791.00 DUPLICATE PLOG / 1.000000e-02 1.060000e+16 -1.280000e+00 5.153000e+02 / PLOG / 1.000000e-01 1.070000e+16 -1.280000e+00 5.130000e+02 / PLOG / 3.160000e-01 1.130000e+16 -1.290000e+00 5.206000e+02 / PLOG / 1.000000e+00 1.420000e+16 -1.310000e+00 6.457000e+02 / PLOG / 3.160000e+00 2.200000e+16 -1.360000e+00 1.066000e+03 / PLOG / 1.000000e+01 5.980000e+15 -1.180000e+00 1.429000e+03 / PLOG / 3.160000e+01 2.390000e+69 -1.923000e+01 1.476000e+04 / PLOG / 1.000000e+02 9.810000e+10 1.900000e-01 8.306000e+02 / O2+C2H3=CO+CH3O 3.0900e+13 -0.890 3682.00 DUPLICATE PLOG / 1.000000e-02 8.190000e+18 -2.660000e+00 3.201000e+03 / PLOG / 1.000000e-01 4.060000e+14 -1.320000e+00 8.858000e+02 / PLOG / 3.160000e-01 4.340000e+14 -1.330000e+00 9.006000e+02 / PLOG / 1.000000e+00 1.030000e+11 -3.300000e-01 -7.478000e+02 / PLOG / 3.160000e+00 1.890000e+12 -3.000000e+00 -8.995000e+03 / PLOG / 1.000000e+01 1.930000e+24 -5.630000e+00 1.800000e+00 / PLOG / 3.160000e+01 1.100000e+18 -2.220000e+00 5.178000e+03 / PLOG / 1.000000e+02 5.790000e+32 -6.450000e+00 1.681000e+04 / O2+C2H3=CO+CH3O 3.0900e+13 -0.890 3682.00 DUPLICATE PLOG / 1.000000e-02 1.290000e+09 1.800000e-01 -1.717000e+03 / PLOG / 1.000000e-01 5.990000e+11 -2.930000e+00 -9.564000e+03 / PLOG / 3.160000e-01 2.910000e+11 -2.930000e+00 -1.012000e+04 / PLOG / 1.000000e+00 5.770000e+21 -3.540000e+00 4.772000e+03 / PLOG / 3.160000e+00 4.990000e+15 -1.620000e+00 1.849000e+03 / PLOG / 1.000000e+01 9.330000e+16 -1.960000e+00 3.324000e+03 / PLOG / 3.160000e+01 1.020000e+72 -2.069000e+01 1.586000e+04 / PLOG / 1.000000e+02 1.100000e+09 3.100000e-01 1.024000e+03 / O2+C2H3=CO2+CH3 6.1600e+13 -1.050 3743.00 DUPLICATE PLOG / 1.000000e-02 2.370000e+35 -7.760000e+00 1.263000e+04 / PLOG / 1.000000e-01 1.730000e+35 -7.720000e+00 1.252000e+04 / PLOG / 3.160000e-01 4.470000e+34 -7.550000e+00 1.214000e+04 / PLOG / 1.000000e+00 7.250000e+31 -6.700000e+00 1.044000e+04 / PLOG / 3.160000e+00 3.630000e+35 -7.750000e+00 1.283000e+04 / PLOG / 1.000000e+01 2.090000e+35 -7.530000e+00 1.405000e+04 / PLOG / 3.160000e+01 3.840000e+18 -2.440000e+00 5.408000e+03 / PLOG / 1.000000e+02 1.210000e+32 -6.320000e+00 1.619000e+04 / O2+C2H3=CO2+CH3 6.1600e+13 -1.050 3743.00 DUPLICATE PLOG / 1.000000e-02 6.270000e+13 -1.160000e+00 4.063000e+02 / PLOG / 1.000000e-01 6.240000e+13 -1.160000e+00 4.014000e+02 / PLOG / 3.160000e-01 6.120000e+13 -1.160000e+00 3.970000e+02 / PLOG / 1.000000e+00 5.320000e+13 -1.140000e+00 4.467000e+02 / PLOG / 3.160000e+00 1.450000e+14 -1.260000e+00 9.877000e+02 / PLOG / 1.000000e+01 5.020000e+13 -1.110000e+00 1.409000e+03 / PLOG / 3.160000e+01 1.400000e+70 -2.011000e+01 1.543000e+04 / PLOG / 1.000000e+02 9.210000e+08 2.500000e-01 8.553000e+02 / CH2(S)+C2H4=CH3+C2H3 1.7700e+19 -1.940 6790.00 DUPLICATE PLOG / 1.000000e-02 1.770000e+19 -1.940000e+00 6.790000e+03 / PLOG / 1.000000e-01 1.680000e+19 -1.800000e+00 4.310000e+03 / PLOG / 1.000000e+00 4.160000e+24 -3.190000e+00 9.760000e+03 / PLOG / 1.000000e+01 7.890000e+24 -3.070000e+00 1.390000e+04 / PLOG / 1.000000e+02 7.360000e+29 -4.280000e+00 2.380000e+04 / CH2(S)+C2H4=CH3+C2H3 4.3000e+12 0.190 -110.41 DUPLICATE PLOG / 1.000000e-02 4.300000e+12 1.900000e-01 -1.104100e+02 / PLOG / 1.000000e-01 2.260000e+11 5.400000e-01 4.781000e+01 / PLOG / 1.000000e+00 4.920000e+09 1.020000e+00 5.997700e+02 / PLOG / 1.000000e+01 1.470000e+08 1.330000e+00 1.228400e+03 / PLOG / 1.000000e+02 8.110000e+10 5.500000e-01 5.506500e+03 / CH2O+C2H3=HCO+C2H4 1.0000e+11 0.000 0.00 PLOG / 1.000000e-03 1.110000e+07 1.090000e+00 1.807200e+03 / PLOG / 1.000000e-02 2.470000e+07 9.930000e-01 1.994900e+03 / PLOG / 1.000000e-01 2.470000e+08 7.040000e-01 2.596200e+03 / PLOG / 1.000000e+00 1.420000e+10 2.090000e-01 3.934200e+03 / PLOG / 1.000000e+01 3.450000e+13 -7.260000e-01 6.944300e+03 / PLOG / 1.000000e+02 3.310000e+14 -8.660000e-01 1.096570e+04 / PLOG / 1.000000e+03 1.650000e+01 3.170000e+00 9.399800e+03 / O+OH+M=HO2+M 1.0000e+16 0.000 0.00 O2+C2H5=>CH3O+CH2O 1.0000e+14 0.000 24000.00 O2+C2H5=>O+CH3+CH2O 1.0000e+13 0.000 27000.00 HO2+C2H5=>OH+CH3+CH2O 5.0000e+12 0.000 0.00 H+CH3O2=CH3O2H 5.0000e+13 0.000 0.00 CH3O2=OH+CH2O 1.5000e+13 0.000 47000.00 OH+CH3O2=>HO2+CH3O 3.0000e+12 0.000 0.00 HO2+CH3O2=>O2+H2O+CH2O 5.0000e+10 0.000 0.00 CH3O2+CH3O=>CH3O2H+CH2O 6.0000e+11 0.000 0.00 CH3O2H+CH3O=>OH+CH3OH+CH2O 1.5000e+11 0.000 6500.00 CH3O2+CH2O=>H2+OH+CO+CH2O 2.0000e+11 0.000 11000.00 CO+CH3O2=>CO2+CH3O 1.0000e+14 0.000 24000.00 CH2+HCO=CO+CH3 2.0000e+13 0.000 0.00 O+CH2=H2+CO 5.0000e+13 0.000 0.00 OH+CH2=H+CH2O 3.0000e+13 0.000 0.00 CO2+CH2=CO+CH2O 1.1000e+11 0.000 1000.00 O+CH2(S)=2H+CO 3.0000e+13 0.000 0.00 CH3+CH=H+C2H3 3.0000e+13 0.000 0.00 CH4+CH2(S)=2CH3 4.3000e+13 0.000 0.00 2CH3=>H2+C2H4 5.0000e+14 0.000 32000.00 C2H6=H2+C2H4 3.0000e+13 0.000 78500.00 H+CH3OH=>H2O+CH3 6.5000e+11 0.000 5300.00 O+CH2O=>2H+CO2 2.0000e+13 0.000 5000.00 OH+CH2O=>H2+H+CO2 1.0000e+11 0.000 0.00 CH2O+HCO=CO2+CH3 5.0000e+11 0.000 8000.00 CO+CH3O=CO2+CH3 5.0000e+11 0.000 6500.00 O2+C2H4=>2CH2O 1.0000e+14 0.000 48000.00 O2+C2H4=>CH3O+HCO 1.0000e+14 0.000 43000.00 O+CH3+M=>CH3O+M 5.0000e+16 0.000 0.00 HO2+HCO=H2O2+CO 4.0000e+11 0.000 0.00 OH+CH3O=>H2O+CH2O 1.5000e+13 0.000 0.00 CH3O+HCO=2CH2O 1.0000e+13 0.000 0.00 CH3O+HCO=>CO+CH3OH 1.0000e+13 0.000 0.00 C2H6+C2H3=>C2H5+C2H4 6.1020e+05 2.000 5704.86 HCO+C2H6=>CH2O+C2H5 1.1340e+06 2.000 15407.96 C2H5+C2H4=>C2H6+C2H3 1.6000e+05 2.000 12804.86 O+C2H4=>OH+C2H3 1.8800e+07 2.000 8057.53 HO2+C2H4=>H2O2+C2H3 6.4000e+06 2.000 24887.96 H2O2+C2H3=>HO2+C2H4 5.4240e+04 2.000 837.96 CH2O+C2H5=>HCO+C2H6 1.6000e+05 2.000 5307.96 O+CH3O2H=>OH+CH3O2 4.7000e+06 2.000 2500.00 OH+CH3O2H=>H2O+CH3O2 3.0000e+09 1.000 50.00 CH3O2H+CH3O=>CH3O2+CH3OH 8.5600e+04 2.000 1500.00 END