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{"sheet":"Table_S6","index":0,"n_rows":3092,"n_cols":144,"rows_kept":562,"cut":true,"merged":[[4,6,4,10],[4,11,4,14],[4,15,4,18],[4,20,4,52],[4,53,4,81],[4,82,4,114],[4,115,4,143]],"bounds":{"rows_first":250,"rows_last":62,"rows_between":250,"halvings":3}}
["Supplementary table 6 : Statistical analysis of the specificity and inductibility of root features in B. rapa and B. oleracea"]
["Statistical analyses for the comparison between BR and BO were conducted on combined Tem and Cu datasets. Prior validation, performed by analyzing each condition separately, confirmed the consistency of the results. Differential metabolites were identified using unpaired t-tests with Benjamini–Hochberg FDR correction (adjusted p-value < 0.05)."]
["This column indicates features that were detected only upon CuCl₂ treatment. These features are at or below the detection limit (> 0.001 ng Apigenin equivalents per mg of dry sample) in control samples and become clearly detectable under CuCl₂ elicitation, highlighting CuCl₂’s role in expanding the observed metabolite repertoire. This is a qualitative assessment (presence/absence relative to the detection threshold), distinct from statistical tests of treatment effect, which quantify changes in feature abundance."]
[]
[{"$nulls":6},"BR/BO comparison",{"$nulls":4},"BR_Cu/BR_Control comparison",{"$nulls":3},"BO_Cu/BO_Control comparison",{"$nulls":4},"Brassica rapa Control",{"$nulls":32},"Brassica oleracea Control",{"$nulls":28},"Brassica rapa CuCl2",{"$nulls":32},"Brassica oleracea CuCl2"]
["Concat_ID","ID","Exp. m/z","RT","Chemical_Family_annotation","Putative_name_annotation","FC","log2(FC)","p.ajusted","log2(FC)_color","Specificity","FC","log2(FC)","p.ajusted","Effect of CuCl2","FC","log2(FC)","p.ajusted","Effect of CuCl2","CuCl₂-dependent detection*","Chiifu_Tem_1","Chiifu_Tem_2","Chiifu_Tem_3","PBD01_R500_Tem_1","PBD01_R500_Tem_2","PBD01_R500_Tem_3","PBD02_Sampad_Tem_1","PBD02_Sampad_Tem_2","PBD02_Sampad_Tem_3","PBD03_Soloveckaja_Tem_1","PBD03_Soloveckaja_Tem_2","PBD03_Soloveckaja_Tem_3","PBD04_Terauchikabu_Tem_1","PBD04_Terauchikabu_Tem_2","PBD04_Terauchikabu_Tem_3","PBD05_Komatsuna_Tem_1","PBD05_Komatsuna_Tem_2","PBD05_Komatsuna_Tem_3","PBD06_Wutacai_Tem_1","PBD06_Wutacai_Tem_2","PBD06_Wutacai_Tem_3","PBD07_Round_leaves_Mibuna_Tem_1","PBD07_Round_leaves_Mibuna_Tem_2","PBD07_Round_leaves_Mibuna_Tem_3","PBD08_Winter_turnip_rape_Tem_1","PBD08_Winter_turnip_rape_Tem_2","PBD08_Winter_turnip_rape_Tem_3","PBD09_Kyoto_Sang_Tem_1","PBD09_Kyoto_Sang_Tem_2","PBD09_Kyoto_Sang_Tem_3","PBD10_Chicon_Tem_1","PBD10_Chicon_Tem_2","PBD10_Chicon_Tem_3","HDEM_Tem_1","HDEM_Tem_2","HDEM_Tem_3","PBD11_C10_Tem_1","PBD11_C10_Tem_2","PBD11_C10_Tem_3","PBD12_CB151_Tem_1","PBD12_CB151_Tem_2","PBD12_CB151_Tem_3","PBD13_Richelain_Tem_1","PBD13_Richelain_Tem_2","PBD13_Richelain_Tem_3","PBD14_po_29.10_Tem_1","PBD14_po_29.10_Tem_2","PBD14_po_29.10_Tem_3","PBD15_nd_125_Tem_1","PBD15_nd_125_Tem_2","PBD15_nd_125_Tem_3","PBD16_Vertus_Verius_Tem_1","PBD16_Vertus_Verius_Tem_2","PBD16_Vertus_Verius_Tem_3","PBD17_RC_Tem_1","PBD17_RC_Tem_2","PBD18_Balady_Tem_1","PBD18_Balady_Tem_2","PBD18_Balady_Tem_3","PBD19_Sel.Mars_Tem_1","PBD19_Sel.Mars_Tem_2","PBD20_bos01_Le_Hode_Tem_1","Chiifu_Cu_1","Chiifu_Cu_2","Chiifu_Cu_3","PBD01_R500_Cu_1","PBD01_R500_Cu_2","PBD01_R500_Cu_3","PBD02_Sampad_Cu_1","PBD02_Sampad_Cu_2","PBD02_Sampad_Cu_3","PBD03_Soloveckaja_Cu_1","PBD03_Soloveckaja_Cu_2","PBD03_Soloveckaja_Cu_3","PBD04_Terauchikabu_Cu_1","PBD04_Terauchikabu_Cu_2","PBD04_Terauchikabu_Cu_3","PBD05_Komatsuna_Cu_1","PBD05_Komatsuna_Cu_2","PBD05_Komatsuna_Cu_3","PBD06_Wutacai_Cu_1","PBD06_Wutacai_Cu_2","PBD06_Wutacai_Cu_3","PBD07_Round_leaves_Mibuna_Cu_1","PBD07_Round_leaves_Mibuna_Cu_2","PBD07_Round_leaves_Mibuna_Cu_3","PBD08_Winter_turnip_rape_Cu_1","PBD08_Winter_turnip_rape_Cu_2","PBD08_Winter_turnip_rape_Cu_3","PBD09_Kyoto_Sang_Cu_1","PBD09_Kyoto_Sang_Cu_2","PBD09_Kyoto_Sang_Cu_3","PBD10_Chicon_Cu_1","PBD10_Chicon_Cu_2","PBD10_Chicon_Cu_3","HDEM_Cu_1","HDEM_Cu_2","HDEM_Cu_3","PBD11_C10_Cu_1","PBD11_C10_Cu_2","PBD11_C10_Cu_3","PBD12_CB151_Cu_1","PBD12_CB151_Cu_2","PBD13_Richelain_Cu_1","PBD13_Richelain_Cu_2","PBD14_po_29.10_Cu_1","PBD14_po_29.10_Cu_2","PBD14_po_29.10_Cu_3","PBD15_nd_125_Cu_1","PBD15_nd_125_Cu_2","PBD15_nd_125_Cu_3","PBD16_Vertus_Verius_Cu_1","PBD16_Vertus_Verius_Cu_2","PBD16_Vertus_Verius_Cu_3","PBD17_RC_Cu_1","PBD17_RC_Cu_2","PBD17_RC_Cu_3","PBD18_Balady_Cu_1","PBD18_Balady_Cu_2","PBD18_Balady_Cu_3","PBD19_Sel.Mars_Cu_1","PBD19_Sel.Mars_Cu_2","PBD19_Sel.Mars_Cu_3","PBD20_bos01_Le_Hode_Cu_1"]
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["p1278_276.109_5.06","p1278",276.109,5.06,null,null,50.979,5.6718,{"v":4.4721e-46,"d":"4.47E-46"},{"$f":"ROUND(H8,1)","v":5.7},"B. rapa",1.3315,0.41304,0.43068,null,0.23828,-2.0693,0.53321,null,null,0.016083329083294316,0.034748469331027494,0.041292175202895194,6.9954615926708956E-3,3.1422529067010596E-3,0.013444976086125552,8.782225100165932E-4,1.7878781945432512E-3,2.3668256046643775E-3,0.02112714278635981,0.005058882492308022,3.4024582162991293E-3,0.005883559101874189,0.014366435120866905,0.005955054456541029,4.919793056323821E-3,5.1269688944663334E-3,3.387086006042539E-3,0.05084067368662668,0.026752613240418117,0.012037872151281466,0.011926599109500119,0.013522167957598199,0.005897759452995466,0.04228645083894598,0.027416915672362988,0.011071537834066537,0.024938022775370352,0.01974145338201832,0.01685282018369859,0.015504038035892962,0.017752523624097818,0.009207516339869281,5.1602398710260545E-5,6.025261188211446E-5,1.0572209546614861E-4,0.012655648543577763,1.5725185070101992E-4,2.8540973771427577E-4,1.8932125111725297E-4,1.8823637515928473E-4,1.3948339483394831E-4,6.1934402309734091E-5,1.460207758275564E-4,1.1991331567541535E-4,1.0607509832021857E-4,4.2077061131958813E-5,9.0889417874918848E-5,9.3571304799861365E-5,1.9498518927830571E-4,8.407322506699383E-5,2.8212363495361686E-5,9.02138951104069e-05,3.9761314465305915E-5,1.5058438258709275E-4,8.6678808579138269E-5,3.1880872817330441E-5,1.1889153754469606E-4,5.7630915709885183E-4,4.1849494730585253E-5,1.0367179450513955E-4,4.8958979369428323E-5,0.044992705462797856,0.042578885658648966,0.031981772631375666,0.036585845490498835,0.030068719992624476,0.027249406571440465,0.014843220143276296,0.01059789025452434,3.4430581331035275E-3,7.5199361567830452E-4,0.017405539461892754,0.011451206290191045,0.012287988640519783,0.01604229582606741,0.012290932494054671,2.263260130369349E-3,0.005936037107053068,0.010767995982787987,0.017715482658577694,0.057012726054922976,0.01781700711451743,0.009213392040579657,0.015886730685290264,0.009960555439092427,0.017333528370159366,0.0173526418062367,0.059910734721904335,0.005944939232262426,0.028169999525258865,0.034242891631901286,0.003937835922980299,0.016200836227056904,0.017801047938092004,1.1542230710323158E-4,1.2501886060397043E-4,7.4657375970990276E-5,6.12640593161764e-05,7.5116507235712529E-5,9.3188399486465368E-5,5.9402081901537118E-5,3e-07,6.3064658990256859E-5,2.2900425642888409E-4,1.0237868890653777E-4,4.6844676437127754E-5,9.1239379998491629E-5,9.6316617753392029E-4,1.1590976953771817E-4,1.0386284708711923E-4,2.2483685037869764E-5,1.3318726937269372E-4,7.5562579649875915E-5,1.8355045228050508E-5,6.2998664428314121E-5,2.0612623924245988E-4,1.8062634507493456E-5,9.8278882331882982E-5,9.3589304079533757E-5,2.3846437286650864E-4,8.1330841633563578E-5,2.0789431450262362E-4,2.5767628496428912E-4]
["n27_320.1002_5.06","n27",320.1002,5.06,null,"Polynitrogen heterocycle conjugated to leucine",46.828,5.5493,{"v":2.0967e-41,"d":"2.10E-41"},{"$f":"ROUND(H9,1)","v":5.5},"B. rapa",0.85794,-0.22106,0.99695,null,0.068298,-3.872,0.48666,null,null,0.01961697560675017,0.030112143512102296,0.08810747386323188,5.758941619875395E-3,1.7676525491942252E-3,0.03442396669181016,3.2658664113269546E-4,1.8908563833193546E-3,0.00666630206909124,0.038582276049837314,5.8656797483863645E-3,0.010477162232363543,0.006047762432120108,0.01425890866561895,0.015456724825577021,0.009458155584317281,0.006421502618111819,0.008665996913456528,0.07728779840848807,0.03640510068435823,0.04072664272157043,0.020998757774410577,0.018783303976331517,0.01113064201432661,0.11485893446136072,0.02886427048567143,0.03622712003419067,0.04301642996379838,0.016138393877183882,0.04372198114376576,0.02644101879550569,0.01741332933727944,0.030323796594503263,9.7252697413216055E-5,2.8404424907009329E-5,4.1760491299897652E-4,0.024310904350650538,6e-08,2.4272484679724502E-4,9.5125732746106963E-5,4.5680636688269011E-5,1.614803750726081E-4,1.5704024402243434E-5,7.0332392815360267E-5,1.5222870310362208E-4,3.1114222533364451E-5,1.0054891499512649E-4,9.4203463878920281E-5,3.987166083853059E-5,4.662280208379014E-4,5.2029259084473818E-5,1.8309934340468693E-5,6.6325563767292032E-5,5.9039275619161456E-6,1.8467442139345245E-5,6.69756624426613e-05,9.5458130843670445E-6,3.5780506138812332E-5,1.4043461389212264E-3,2.8752800597460795E-5,2.038173612547794E-5,1.7569224574952877E-4,0.05968733823377162,0.04104570426463068,0.03716235319730408,0.057688346466627585,0.030469071071239202,0.03966804234703033,0.025651115255859325,0.010268389304042499,0.003588094189688316,6.4949326030402238E-4,0.021040988240862892,0.012151187604238873,0.01934590679240126,0.02235067957978333,0.013639356128810431,2.4627629532664634E-3,0.007105327593696932,0.010840657209340323,0.021751871761401264,0.05643068389251299,0.01805375650803424,0.014124346315825865,0.013488940837978783,0.011398787176210737,0.018200880687775218,0.02123952325179979,0.04132448878899184,3.9075302185359465E-3,0.029939209153123945,0.040179811205606014,0.002936940292972066,0.013748532577113382,0.021640503178330196,7.8350192370340747E-5,1.0438695163104613E-4,5.033411515996137E-5,3.9651383978206236E-5,1.3641722884639745E-5,1.8527454225990155E-5,1.7539463793535453E-5,3.587664975338893E-5,4.0785334634992957E-5,4.2648883374689826E-5,5.36477142241761e-05,3.8856508465167921E-5,3.9036509712975891E-5,7.3181384857727181E-4,3.5159143066662656E-5,5.211709779535286E-5,6.703616361612221E-6,3.6319511276622462E-5,3.3908239459987071E-5,6e-08,4.6293402329527494E-5,5.370272779743533E-5,8.3513262917647358E-6,2.8121255337859933E-5,7.39212936226384e-05,9.8111712025209419E-5,6.7528580186808042E-5,2.5880463946929207E-5,5.9649246732045389E-5]
["p1286_464.14_3.48","p1286",464.14,3.48,null,null,43.624,5.4471,{"v":1.4714e-56,"d":"1.47E-56"},{"$f":"ROUND(H10,1)","v":5.4},"B. rapa",0.88167,-0.18169,0.9465,null,1.095,0.13098,0.93877,null,null,0.01671798053297248,0.023349082631944636,0.0316098303176263,0.003725440451021846,0.001870056711492138,5.8933083756667545E-3,4.4662845822402465E-3,0.010461777885105583,0.011235417644588287,0.025035263271058757,0.011425401215707716,0.008926121096858034,0.011378734459083318,0.008350208391219782,0.004580659437928745,0.022551757664947505,0.009862350400930121,6.87654123434392E-3,0.051923076923076926,0.01183673469387755,0.008381198565553432,0.019889863811025817,0.019654989065814973,0.006571977755931506,0.030731042756094677,0.020872046247617716,0.007612446671145495,0.031849239141388694,0.020710643387300363,0.008492324849811146,0.013280936829642412,0.013934720603189562,0.007706783862970475,5.8669683751013616E-4,6.3003274598471854E-4,2.6294982718503624E-4,2.4244977689258287E-3,2.68944754002679E-4,3.588008131265181E-4,3.9667309757900613E-4,1.7026405793302136E-4,1.8050792272628608E-4,2.7577107554755287E-4,2.0177416296171432E-4,2.759450999277631E-4,2.69267557274401E-4,2.3528805612564726E-4,6.5545253275181857E-5,1.6946802980419336E-4,1.2093158080675403E-4,3.8646563135634259E-4,9.5700762445050422E-5,1.2724907310310025E-4,6.253721304251996E-5,1.410987521879058E-4,1.9605920988138419E-4,6.2167701993794355E-5,1.7270560190703219E-4,2.8227387286474379E-4,1.5693560523969468E-4,1.9393775351392482E-4,1.2689368122280404E-4,0.02628302804344302,0.026441266010257532,0.018536121728296103,0.012642083733643028,0.008467097378144346,0.007526756340315663,0.02652823593186719,0.021743153004935643,0.015040449129597223,2.10222581946257E-3,0.01427521205426922,0.011240311699386234,0.011453970439534434,0.010964186403993749,0.009888471168109503,0.005698963213520197,0.011447253025667011,0.010462011163214152,0.015460757671638112,0.019122375004924943,0.014445447228614317,0.015179657373447857,0.01990768223483195,0.007551440620309769,0.01034786357687274,0.006676783566207087,0.009736989949853305,0.004490420472226206,0.01578204107038301,0.017878745553153635,2.7486785555782467E-3,0.009129756927219897,0.014373774997852586,6.8301447708510224E-4,3.8885176643028041E-4,4.2185914855896918E-4,2.4034361731730745E-4,1.5105847059489441E-4,0.003590083090216078,1.3090458789412809E-4,3.1304898885778229E-4,1.3321523472099202E-4,2.2003967699572494E-4,3.1070741633263213E-4,1.7656839580148154E-4,2.0399748169474074E-4,0.000301206527441056,1.3966177149216861E-4,1.1475755132702685E-4,4.4967370075739528E-5,1.372232472324723E-4,1.2764940639881951E-4,5.0234860624138239E-5,2.6585436388748557E-4,2.1658950011771167E-4,6.1774210015627619E-5,2.0220597629203512E-4,1.7380870757627702E-4,2.1656458352162518E-4,1.3697825959337024E-4,3.6450192586803614E-4,2.253169375501691E-4]
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["n555_334.1161_6.38","n555",334.1161,6.38,null,"Polynitrogen heterocycle conjugated to homoleucine",16.233,4.0208,{"v":1.0797e-21,"d":"1.08E-21"},{"$f":"ROUND(H32,1)","v":{"v":4,"d":"4.0"}},"B. rapa",0.7729,-0.37165,0.94783,null,0.13884,-2.8485,0.84411,null,null,1.7185399995985268E-3,2.230097210789571E-3,0.00498714585173564,6.3533574340435362E-5,9.5305783425527918E-6,3.7834017354944859E-4,5.1738073784121872E-6,3.7798384665726395E-5,1.8248108650077479E-4,4.041722653738436E-3,0.000976139650620824,9.5721310978947856E-4,6.585643572576507E-4,1.1615072548517963E-3,0.001514066716117866,1.0245585672300124E-3,4.7687383055926383E-4,5.8837234938068713E-4,6.0558248727095336E-3,1.9348136477770669E-3,2.6019045744676097E-3,2.4315279584762738E-3,1.6195181283058145E-3,8.852036639185306E-4,0.004016035257067253,1.7636525652883592E-3,0.002810063761564757,6.848231690336954E-3,1.5479997940705031E-3,3.0870395526942694E-3,0.002394884918384662,1.4764170381748023E-3,0.002102800363946217,4.9028219357075858E-5,3.5843679049321292E-5,7.505970658478336E-5,0.004478749340526599,6e-08,7.0141020367264724E-5,4.0356371468045375E-5,2.9558059033585827E-5,6.1571653804663523E-5,1.5428515202204075E-5,6e-08,6e-08,6e-08,4.5486413926366732E-5,5.46107036979248e-06,3.0282274054580193E-5,3.3810428992061543E-5,6e-08,9.7154753643303263E-6,6e-08,2.330497721809005E-6,6e-08,1.9319902627690757E-5,1.2309074766683821E-5,2.0345778000501129E-5,1.5845298150303971E-4,6e-08,2.2527182033422989E-5,5.8564081916509583E-5,0.005259343617351694,1.9809549400637426E-3,2.8098841569408305E-3,5.3586959372437166E-4,2.5615716382009282E-4,3.5947126024283752E-4,3.0848973713834744E-4,1.5125596470694157E-4,5.8072626946124358E-5,3.8852693707969581E-5,0.002750445953112468,1.2452666850298606E-3,2.0377203772037724E-3,1.8822288535706214E-3,1.5778644395986212E-3,1.9417938669985576E-4,8.6473677974803519E-4,5.7387686300866645E-4,1.1598092925116331E-3,0.004369077436122392,1.4264914023276935E-3,1.3192291324700593E-3,1.2973685787927834E-3,1.0592228618601608E-3,1.0395377554111042E-3,9.8371483383014329E-4,2.6734645395903004E-3,5.4041807662838482E-4,0.00429907772115851,3.3497919807403817E-3,1.3161270897240002E-4,7.1008824445606259E-4,1.1303543497477718E-3,6e-08,4.4994375703037125E-5,2.2650351821982621E-5,1.936462938470537E-5,1.3073317764446422E-5,6e-08,9.8327297024365433E-6,3.2823317859483492E-5,6e-08,1.9385856079404466E-5,8.6021334876696165E-5,3.8094616142321495E-5,4.3074769338456156E-5,8.74710025564682e-05,3.8355428799995621E-5,2.25371233709634E-5,9.2573749755597338E-6,3.2804719862755769E-5,2.3735767621990954E-5,1.6615824338622122E-6,6e-08,2.8106100529498861E-5,5.9911688614833982E-6,3.954551531886553E-5,5.6595990429832525E-5,6e-08,2.4613220815752462E-5,1.4788836541102404E-5,1.7266887211907874E-5]
["n155_461.1303_2.91","n155",461.1303,2.91,null,null,16.2,4.018,{"v":1.5776E-16,"d":"1.58E-16"},{"$f":"ROUND(H33,1)","v":{"v":4,"d":"4.0"}},"B. rapa",1.0067,0.0096187,0.8618,null,0.81107,-0.30211,0.82591,null,null,4.34618406439635E-5,1.1057619329113502E-4,8.6010731565833035E-4,1.5492141630131019E-3,8.3521433097566412E-4,0.011133179304733114,6.9870278719541806E-4,0.00674748023784868,0.022700391942393584,0.009696773269052297,0.003369332272311975,0.005717187671076511,1.4605636853036743E-3,0.005317349512079237,0.008349189967856722,8.2340820207551688E-4,9.1790065335439167E-4,1.224095081572935E-3,0.016606832525381872,0.009878784894884547,0.012746514467698722,0.010849260177481801,0.00847528994346613,0.008059358163227058,0.02067532564336694,0.00663805027167123,0.009085031996096614,5.0348092453355621E-4,1.0608839812881817E-3,2.4368804872371254E-3,0.007811600556255688,0.004491664481324692,0.00974230104514185,3.142628486658469E-4,2.475242741896527E-4,6.3323097918799049E-4,1.9158122742294614E-3,6.5225646610491317E-4,1.3483688257443917E-3,2.4213822880827227E-4,1.0009433627282474E-4,3.3573977263297652E-4,1.8817278362688185E-4,7.1777578969100544E-4,2.036436955425938E-4,1.9244722826192086E-4,2.3581114588142751E-4,3.493478839499601E-5,9.6903276974656633E-5,3.6924547451856689E-4,8.5394053798961789E-4,4.8502642395772174E-4,1.8623177904855332E-3,1.0202401137697201E-5,7.4429388016149025E-5,3.1040643555156486E-4,1.4821130841517253E-5,5.4021548484089205E-5,2.363213038416764E-4,2.3890963405526512E-4,6.339792657977612E-4,5.6123911836655015E-5,1.276874762742865E-4,3.4506102433072881E-4,1.2677183141465709E-4,0.017707513019292017,0.011953622327622334,0.011747114061845806,0.02930781578018124,0.01489556135770235,0.012809233193150695,6.1072652388301739E-4,0.00864710755030395,0.005210505764731166,4.5218896633410785E-3,0.006383606826419453,5.3431536658855045E-3,3.8813324565673847E-4,8.1663441412266509E-4,5.7045277671386526E-4,0.005630070347980965,7.784766540727431E-3,0.00927930963043853,0.009570043592852061,0.012831025594916983,0.009613538661502725,0.004356795042054007,0.005046572958521772,0.007908313993506694,4.86601286901686E-5,2.4646637222038958E-4,3.8481325130864421E-4,6.4506380914234175E-4,1.799813200417111E-3,5.3664395827831115E-3,4.0989521692694057E-4,2.7896512935883018E-4,2.0888657791383973E-4,1.2070618983133013E-3,5.320271925009501E-4,1.3966850108823347E-3,6.6437362854300969E-5,1.8090991471389736E-4,2.9243952706367289E-4,3.1986662531017373E-4,1.9701660568533636E-4,2.9866179055580049E-4,1.9585559183579284E-4,2.3258418652111586E-4,1.7771348677331303E-4,3.8970442495624209E-5,1.7493246505540463E-4,9.9702916440018419E-4,0.00063804003917209,6.2553691627753867E-6,8.6879398892400928E-5,6.3238726191372437E-5,1.706575372664968E-5,5.1848564529179258E-5,1.3975744575530074E-4,8.5847748022058233E-4,0.000649410364600238,4.9296121803674685E-4,5.7294671203148851E-5]
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